| Louise-Françoise de Bourbon - Mayor of the Palace | Legitimate daughter of Louis XIV, Duchess of Bourbon. |
| Bernard Poyet - Architect | Author of the neo-classical facade under Napoleon I. |
| Jules de Joly - Architect | Manufacturer of the current hemicycle (1827-1832). |
| Eugène Delacroix - Painter | Decorate the palace library. |
| Auguste Vaillant - Anarchist | Author of the 1893 attack in the Chamber. |
| Jean-Pierre Cortot - Sculptor | Author of the allegorical fronton (1841). |