| Baron Haussmann - Urbanist | Manufacturer of the boulevard under the Second Empire. |
| Germain de Paris - Bishop of Paris (496–576) | Inspiration of the name of the boulevard. |
| Guillaume Apollinaire - Poet | Lived in no 202 until 1918. |
| Yves Montand - Singer and actor | Last home at number 114. |
| Carlos - Terrorism | Author of the 1974 bombing. |
| Charles Garnier - Architect | Designed several buildings on the boulevard. |