| Ebbon - Archbishop of Reims | Founded the college in the 9th century. |
| Hincmar - Archbishop of Reims, successor of Ebbon | Dota the church with a chapter of canons. |
| Étienne Cagniart - Prevost of the chapter (17th century) | Becoming parish priest of Charleville in 1677. |
| Pierre-Louis-Hector de Singly - Last Provost (1789) | Named with eleven canons before the Revolution. |
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