| Angélique Arnauld - Reformative abbesse (1626-1661) | Founder of the Abbey, promoter of the recount. |
| Antoine Lepautre - Architect of the chapel | Designed the chapel (1646-1648) and its aborted decor. |
| Agnès Arnauld - Abbess (1661-1671) | Author of the Constitutions for converse sisters. |
| Marguerite Périer - Nièce de Blaise Pascal | Miraculously cured in the abbey (Jansenist testimony). |
| Alexandre Minkowski - Neonatologist (XX century) | Created the first neonatology service in Port-Royal. |
| Chrétien Guillaume de Lamoignon de Malesherbes - Prisoner in 1794 | Held at *Freeport* before execution. |
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