| Baudouin VII - Count of Flanders | Founded the college in 1113. |
| Antoine-Joseph Lefebvre - Architect of Douai | Designed the current building. |
| Charles-Joseph de Pollinchove - President of Parliament | Sponsor of the college in 1740. |
| Charles Mutin - Organ factor | Installed the Cavaillé-Coll organ in 1922. |
| Christophe-Gabriel Allegrain - Sculptor | Realized Pollinchove mausoleum. |
| Thomas de Cantimpré - Abbé and columnist | Described the Eucharistic miracle of 1254. |
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