| Napoléon Bonaparte - Founder (1802) | First Consul, merges the schools of Metz and Châlons. |
| Jean-Victor Poncelet - Teacher and student | Mathematician, French engineer and general. |
| Sadi Carnot (physicien) - Student (1814-1817) | Physician and politician. |
| Michel Maunoury - Student (1869) | Marshal of France during the First World War. |
| Guillaume Henri Dufour - Student | Swiss general and cartographer. |
| Basile Guy Marie Victor Baltus de Pouilly - Commander (1815) | Brigadier General of the First Empire. |
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