| Nicolas Largentier (V) - Owner and manufacturer | Finish the hotel around 1536. |
| Nicolas Largentier (VI) - Baron de Chapelaines | Enriched under Henry IV, renamed the hotel. |
| Louis XIII - King of France | Stayed in 1629 to assert his authority. |
| François Ier d’Autriche - Emperor of Austria | Held anti-Napoleon conference in 1814. |
| Victor Paillot - Mayor of Troyes and Member of Parliament | Owner in the 19th century via his wife. |
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