| François Mansart - Architect | Designed the hotel for La Vrillière (1635-1650). |
| Louis Ier Phélypeaux - Lord of La Vrillière | Initial sponsor, Secretary of State under Louis XIII. |
| Louis-Alexandre de Bourbon - Count of Toulouse | Son of Louis XIV, acquirer in 1713. |
| Robert de Cotte - Architect | Redesign of the hotel for the Count of Toulouse. |
| Princesse de Lamballe - Intimate by Marie-Antoinette | Wedding celebrated in the Golden Gallery (1767). |
| François-Antoine Vassé - Sculptor | Author of the rock woodwork (1718). |