| Urbain Loir Mongazon - Founder | Abbed originally from the institution in 1833 |
| David d’Angers - Sculptor | Author of the statue of the founder in the chapel |
| Louis Bonn - Organ factor | Creator of romantic organ (circa 1860) |
| Jean Foyer - Former student and minister | Garde des Sceaux (1962-1967), CDI on his behalf |
| Jean-Paul Proust - Former student | Police prefect and then Minister of State of Monaco |
| François Gourdon - Former student | Bishop of Saint-Dié (Vosges) since 2015 |
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