| Jérôme Champion de Cicé - Archbishop of Bordeaux | Founder of the institution in 1786. |
| Roch-Ambroise Sicard - Director and disciple of the Abbé of the Sword | First director, left for Paris in 1790. |
| Jean de Saint-Sernin - Lay Director (1790–1816) | Student of Sicard, runs the school until his death. |
| Joseph-Adolphe Thiac - Departmental architect | Manufacturer of the building (1861–170). |
| Louis-André de Coëffard - Sculptor | Author of the statue of the Abbé of the Sword. |
| Abbé de L’Épée - Pioneer of Deaf Education | Inspiring the teaching method used. |
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