| Odon de Tournon - Ancestor of the Counts of Tournon | Reported the first Black Virgin |
| Antoine Farigoules (1723-1797) - Purchaser of the chapel in 1789 | Safeguarding furniture and sacred objects |
| Père Joseph Laurent (1749-1809) - First post-revolutionary chaplain | Served the sanctuary 12 years |
| Jeanne de Larochette (1768-1849) - Restoration of the sanctuary | Financed works 1831-1834 |
| Abbon-Pierre-François Bonnel de la Brageresse - Bishop of Viviers (1835) | Blessed chapel and entrusted to the Jesuits |
| Joseph-Michel-Frédéric Bonnet - Bishop of Viviers (1890) | Coronation Chair Black Virgin |
| Saint Jean-François Régis - Jesuit Missionary | Famous Pilgrim of the Shrine |
| Saint Jean-Marie Vianney - Curé d'Ars | Visita Our Lady of Ay |