| Ferdinand-Maximilien-Mériadec de Rohan-Guéméné - Archbishop of Bordeaux (1769-1781) | Sponsor of the palace, ruined by its construction. |
| Joseph Étienne - Initial architect engineer | Author of the first plans (1771). |
| Richard-François Bonfin - Senior Architect | Finished the palace and drew the honorary staircase. |
| Barthélemy Cabirol - Sculptor decorator | Realized panelling and pediments (1781). |
| Eugène Delacroix - Romantic painter | Discovered his vocation in the dining room. |
| Charles Burguet - 19th century architect | Designed the wings of the museum (1880). |
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