| Claude Rosalie Liautard - Founder | Abbed originally from the college in 1804. |
| Louis XVIII - Protective monarch | Renamed the establishment in 1822. |
| Henri Lacordaire - Preacher | Gives his first lectures in 1834. |
| Charles de Gaulle - Former student | Future president, educated in 1908-1909. |
| Daniel Chapellier - Controversial Director | Charged for sexual assault in 2021. |
| Amélie Oudéa-Castéra - Minister and student parent | Critiqued for Stanislas' choice in 2024. |
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