| Jeanne Ire de Naples - Queen and Countess of Provence | Initial recipient of the palace (1348). |
| Hugues IV des Baux - Sénéchal de Provence | Sponsor of the palace in 1346. |
| Urbain V - Pope (1362–1370) | Offered the palace to Cardinal de la Roche. |
| Androin de la Roche - Cardinal and Abbé de Cluny | First occupant of the cardinaly livery. |
| Pierre de Cros - Cardinal Archbishop of Arles | Founded the college in 1380. |
| Jean-Henri Fabre - Naturalist and conservative | Teaching at the museum (1866–70). |
| Stéphane Mallarmé - Poet and Professor | English was taught in municipal courts. |
| Victor Duruy - Minister of Public Education | Support for public courses in Saint-Martial. |
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