| Pierre Le Gendre - Lord of Alincourt and Treasurer of France | Légue Villeroy aux Neufville in 1524. |
| Nicolas III de Neufville - Manufacturer of Renaissance Castle | Founded the estate in the 16th century. |
| Madeleine de l’Aubespine - Poetess and wife of Nicolas IV | 16th century cultural figure. |
| Charles de Neufville - First Marquis de Villeroy | Appointed in 1615, ambassador to Rome. |
| Nicolas V de Neufville - 1st Duke of Villeroy and Marshal | Titled by Louis XIV in 1651. |
| Gabriel Louis François de Neufville - 5th Duke of Villeroy | Last owner before the Revolution. |
| Louis XIV - King of France | Traveled to the castle. |
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