| Aimery VI de Rochechouart - Viscount and builder | Founder of the present castle in the 13th century. |
| Alix de Rochechouart - Protagonist of the Legend | Innocentated by a lion in a dungeon. |
| François de Rochechouart-Pontville - Criminal Viscount | Author of the murder of Bermondet (16th century). |
| Françoise-Athénaïs de Rochechouart (Madame de Montespan) - Favourite of Louis XIV | A prominent figure in the versailalis court. |
| Louis-Victor-Léon de Rochechouart - General and last owner | Napoleon's Veteran sold the castle in 1836. |
| Albert Masfrand - Local archaeologist | Founded the Masfrand Museum in the 19th century. |
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