| Anne d’Autriche - Queen Regent | Founded the hospital in 1651. |
| Charles-Auguste Questel - Architect | Designs the buildings inaugurated in 1867. |
| Jean Delay - Psychiatrist | Codiscoverer of Largactil, President of the 1950 Congress. |
| Pierre Deniker - Psychiatrist | Pioneer of modern psychopharmacology. |
| Jacques Lacan - Psychoanalyst | Internal in Sainte-Anne (1927-28). |
| Georges Eugène Haussmann - Prefect of the Seine | Supervises the creation of a clinical asylum. |