| Marie Delpech de l’Estang - Founder of the institution | First superior mother of orphans. |
| Henri de Sourdis - Archbishop of Bordeaux | Approves the congregation in 1638. |
| Jeanne Durfort - Higher in 1663 | Start building the chapel. |
| Henri de Béthune - Archbishop of Bordeaux | Validates the project in 1663. |
| Julien Foucré - Suspected architect | Possible author of Baroque plans. |
| Clément X - Pope in 1671 | Gives indulgences to visitors. |
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