| Marcel Avril de Pignerolle - Director of the horseback riding academy | Died imprisoned in 1793. |
| Pierre-Antoine Blancler - Negotiator and Mayor of Saint Barthélemy | Restore the castle in the 19th century. |
| Michel Bardoul de la Bigotière - Architect | Designs the neo-classical castle. |
| Władysław Raczkiewicz - President of the Polish Republic | Resides at Pignerolle in 1939-1940. |
| Henri Enguehard - Architect of Historic Monuments | Ranked in 1961. |
| Guy Biraud - Collector and industrial | Founded the Museum of Communication. |
| François Éveilard - Mayor of Angers (1641-1643) | First April owner of Pignerolle. |
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