| Élie Ier du Maine - Count of Maine | Reconstructed the college in 1093. |
| Geoffroy V d’Anjou (Plantagenêt) - Count of Anjou and Maine | Wife Mathilde the Emperor in the palace. |
| Henri II d’Angleterre - King of England and Count of Maine | Born in Le Mans, regularly resides in the palace. |
| Bérengère de Navarre - Queen, widow of Richard Lion Heart | Resides in Le Mans until 1230. |
| Charles II d’Anjou - Apanist Count | Add a bedside to the college. |
| Bertrand du Guesclin - Connétable de France | Stays in the large room in 1370. |
| François Ier - King of France | Offer part of the palace to the city. |
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