| Cardinal François II de Tournon - Founder of the College | Created the establishment in 1536 and bequeathed its library. |
| Stéphane Mallarmé - Former professor | French poet teaching in the 19th century. |
| Gabriel Faure - Homonymous writer | Native of Tournon, gives his name to the high school in 1967. |
| Augustin Pérouse - Professor and writer | Signed the letters from 1901 to 1919. |
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