| Paul de Grivel de Grossouvre - Count of Orrouer | Sponsor of construction in 1732. |
| Pierre Boscry - Architect | Main designer of the hotel. |
| Nicolas Pineau - Sculptor and architect | Author of interior decorations. |
| Prince Richard Klemens von Metternich - Ambassador of Austria | Resident between 1859 and 1861. |
| Hubert Taffin de Givenchy - Couturier and collector | Owner from 1986 to 2018. |
| Xavier Niel - Entrepreneur and billionaire | Current owner since 2019. |
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