| Alexandre-Théodore Brongniart - Architect | Designed the convent of the Capuchins in 1781 |
| Nicolas de Condorcet - Philosopher homonym | High school renowned in his honour in 1883 |
| Clémence Ramnoux - First literary normalist | Former student, received at the ENS in 1927 |
| Anne Chopinet - First woman in Polytechnique | Student received first in 1972 |
| Jean-Paul Sartre - Alternate professor | Replaces Jewish teacher dismissed in 1941 |
| Serge Gainsbourg - Former student | Leave high school in 1941 under anti-Semitic laws |
| Patrick Rouil - Current provider | Head of the establishment since 2018 |