| Jeanne d'Albret - Protestant protector | Promoter of the college in the 16th century. |
| Henri de Navarre - Future Henri IV | Support from the college with his mother. |
| Frère Louis Mercier - Jesuit architect | Manufacturer of the chapel (1631-1638). |
| Antoine Brossard - 19th century architect | Reconstructed the college in 1838. |
| Eugène Fromentin - Rock painting | Gives his name to the college in 1974. |
| Jean-Paul Sartre - Famous student | Studyed in the establishment. |
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