| Élie Decazes (duc) - Founder and Minister of the Interior | Initiator of the museum in 1818, native of the region. |
| Antoine Victor Bertal - Legate | Donations via the city of Creon in 1952. |
| René Princeteau - Local animal painter | Friend of Toulouse-Lautrec, equestrian works exhibited. |
| Nicolas Giboin - Artisan glassmaker from Liechtenstein | Glazed glassware preserved at the museum. |
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