| Nicolas Perrenot de Granvelle - Adviser to Charles Quint | Sponsor of the palace, collector of art. |
| Antoine Perrenot de Granvelle - Diplomate at the service of Charles Quint | Son of Nicolas, heir to the palace. |
| Abbé Boisot - Inventoryist of collections | Open the first public collection. |
| Laurent Mégevand - Swiss watchmaker | Founded the watch industry in Besançon. |
| Eugène Viollet-le-Duc - Architect Inspector | Restoration project in 1870. |
| Louis XIV - King of France | Stayed at the palace in 1683. |
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