| Valerius (saint Valier) - First Bishop of Couserans | Lived between the fourth and fifth centuries. |
| Licerius (saint Lizier) - Bishop and patron saint | Canonized as Saint Lizier. |
| Bernard Coignet de Marmiesse - 17th century bishop | Sponsor of the expansion of the palace in 1660. |
| Jean d’Aule - Bishop from 1475 to 1515 | Period of major frescoes of the cathedral. |
| Dominique de Lastic de Fournels - Last bishop before 1801 | Failed the Revolution in 1792. |
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