| Charles-François d'Hallencourt - Bishop of Verdun (1721-1754) | Initiator of the building of the palace. |
| Robert de Cotte - Architect of King Louis XV | Author of the initial plans of the palace. |
| Jules-Robert de Cotte - Architect, son of Robert de Cotte | Continues work after 1735. |
| Marcel Herriot - Bishop of Verdun (until 1993) | Last bishop to occupy the palace. |
| Javier Pérez de Cuéllar - Secretary-General | Project support in 1988. |
| Édouard Balladur - Prime Minister (1993-1995) | Inaugurate the centre in 1994. |
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