| Jean de Dunois - Companion of Joan of Arc | Freed from Carles in 1451. |
| Vital Carles - Chanoine de Bordeaux | Fonda St. Andrew's Hospital, a prominent member. |
| Lancelot de Carles - Bishop of Riez and poet | Close to the Pleiade, Marguerite's uncle. |
| Marguerite de Carles - Heir and widow of La Boétie | Transmitted the castle in 1567. |
| Marie-Charlotte de Boufflers - Salonière des Lumières | Protected Mozart and Diderot in the 18th. |
| Guillaume Chastenet de Castaing - 19th century restaurant restaurant | Saved the castle, decorated with Tunisian earthenware. |
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