| Palladius - Bishop of Saints (VIth century) | Founder of the Paleo-Christian shrine. |
| Pierre de Confolens - Bishop (1112-1127) | Initiator of the Romanesque Cathedral. |
| Guy de Rochechouart - Bishop (15th century) | Supervises the Gothic reconstruction. |
| François de Coligny d'Andelot - Huguenot chef | Responsible for the destruction in 1568. |
| Louis de Bassompierre - Bishop (1648-1676) | Participates in the reconstruction of the choir. |
| Pierre-Louis de la Rochefoucauld - Last Bishop of Saintes | Victim of the massacres of September (1792). |
| Pie IX - Pope (1846-1878) | Restored the title of cathedral in 1852. |
| Napoléon Bonaparte - First Consul | Offer columns for the high altar. |
| Louis XI - King of France | Visit the cathedral in 1472. |
| Jean-Pierre Blanchard - Contemporary Artist | Author of a portrait of Pope Francis (2013). |
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