| Frédéric Barberousse - Emperor of the Holy Empire | Confessed the right to beat money (1177). |
| Raymond VI de Toulouse - Count of Toulouse | In conflict with the bishop for mines. |
| Burnon - Bishop of Viviers (1210–1216) | Consolidated episcopal power over Largentière. |
| d’Artagnan - Captain of Musketeers | Delivered the castle in 1670. |
| François Grimoard de Beaumont - Marquis de Brison | Aceta and transformed the castle (1714). |
| Claude de Tournon - Bishop of Viviers | Expands the castle (XVI century). |
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