| Boson de Grignols (dit Talleyrand) - First Lord Talleyrand | Receives the seigneury around 1243 |
| Jean de Talleyrand - Knight of Honour of Anne of Brittany | Transform the castle (1495-1505) |
| Louis de Sancerre - Marshal of France | Preacher of the castle in 1376 |
| Vicomte de Turenne - Protestant leader | Stomach of the castle in 1587 |
| André Jouanel - Archivist and Saviour | Buy the castle in 1902 |
| Hélie-Roger-Louis de Talleyrand-Périgord - Last Count of Grignols | Left the estate in 1883 |
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