| Richard Cœur de Lion - Duke of Aquitaine and King of England | The castle was taken in 1188. |
| Jean V de Vendôme - Count of Vendôme | Organised the split of the Vendômois. |
| Jean-Sébastien de Kerhoent - Marquis de Montoire | Obtained the erection in marquisat (1743). |
| Philippe Pétain - French Head of State | Hitler met with Montoire in 1940. |