| Jean Bence - Superior Oratorian | Signatory of the Treaty of 1618. |
| Pierre de Chavanon - Founder of Saint-Amable Abbey (XIe s.) | At the origin of the first Portuguese schools. |
| Marivaux - Writer and playwright (1688–1763) | Famous former college student. |
| Gilbert Romme - Mathematician and revolutionary (1750–1795) | Students then figure of the Revolution. |
| Gabriel Dumontel - Former student and director (1800) | Relaunching school after the Revolution. |
| Jean-Antoine Chaptal - Minister of the Interior under Bonaparte | Supports the reopening of the colleges in 1801. |
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