| Antoine de la Croix - Benefactor | Légua 15,000 pounds to found the college. |
| Jean-Baptiste Caristie - Architect | Designed Notre Dame Church in 1757. |
| Napoléon Bonaparte - Famous student | Studyed at college in 1779. |
| Lazare Carnot - Student and revolutionary | Attended college in 1767. |
| Étienne-Guy Charton - Painter | Author of the paintings of the chapel. |
| Talleyrand - Bishop of Autun | Visited college in 1789. |
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