| André Pottier (1799–1867) - Founder and first curator | Collecteur et historian de la faience rounnaise. |
| Charles Maillet du Boullay - Conservative (1873–75) | Lead the museum after Pottier. |
| Gaston Le Breton - Conservative | Successor of Maillet du Boullay. |
| Pierre Chapelle - Fayencier (XVIII s.) | Author of the heavenly and earthly Spheres. |
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