| Frédéric Engel-Dollfus - Founder and collector | Initiator of the museum in 1864. |
| Jean Dollfus - Industrial and management of DMC | Frédéric Engel-Dollfus's stepfather. |
| Jean Vetter - First owner of the villa | Manufacturer of Indian women, sponsor in 1788. |
| Georges Steinbach - Former owner of the villa | Industrial, acquired in 1840. |
| Jean-Jacques Henner - Symbolic regional painter | Dedicated room in the museum. |
| Hyacinthe Rigaud - Portraitist painter | Author of the *Banquier Jabach* (circa 1688). |
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