| Jean de Goulaine - Captain of Nantes | Fortify the castle in the 12th century. |
| Gabriel de Goulaine - Lord then Marquis | Obtained marquisat in 1621. |
| Clémence Lefeuvre - Chief cook | Invents white butter around 1890. |
| Piter Deurbroucq - Dutch shipowner | Purchase the castle in 1788. |
| Robert de Goulaine - Marquis and wine growers | Buy the estate around 1960. |
| Hervé Lecesne - Industrial in Paris | Recently acquired the castle. |
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