| Guillaume III de Pouancé - Lord of Pouancé (XIIIe s.) | Strengthens the fortress and creates the pond. |
| Pierre II de Valois - Lord and Modernizer (XIVe s.) | Constructed the Big Tower and added mâchicoulis. |
| Jean IV de Bretagne - Duke of Brittany | Asiegea Pouancé in 1379. |
| Jean II d’Alençon - Complot against Louis XI (1467) | Caused the partial destruction of the castle. |
| Louis Bessière - Scenery (XXe s.) | Organised the first search and rescue. |
| Anaïs Casaubon - Contemporary historian | Author of a thesis on the castle (2012). |
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